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Evolution of O2 in a Seven-Coordinate RuIV Dimer Complex with a [HOHOH]− Bridge: A Computational Study

✍ Scribed by Jonas Nyhlén; Lele Duan; Björn Åkermark; Licheng Sun; Timofei Privalov

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 594 KB
Volume: 122
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200906439

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## Abstract A pentadentate phenol‐containing ligand (H~3~L) with N~2~O~3~ donor atoms yields Ni^II^~2~ (1), Ni^II^~4~ (2), Cu^II^~2~ (3) and Cu^II^~4~ (4) complexes, which have been structurally characterized by X‐ray diffraction. Complex 1 contains a single‐atom __O__‐bridged urea. The compounds w