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Evolution from Hydrogen Bond to Proton Transfer Pathways in the Electroreduction of α-NH-Quinones in Acetonitrile

✍ Scribed by Macı́as-Ruvalcaba, N. A.; González, I.; Aguilar-Martı́nez, M.


Book ID
127100732
Publisher
The Electrochemical Society
Year
2004
Tongue
English
Weight
185 KB
Volume
151
Category
Article
ISSN
0013-4651

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Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho