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Evidence that 8-methoxypsoralen (8-MOP) is a T-lymphocyte immunomodulatory agent

✍ Scribed by George W. Cox; Charles G. Orosz; Mark G. Lewis; Richard G. Olsen; Richard H. Fertel

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
677 KB
Volume
10
Category
Article
ISSN
0192-0561

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Oxidation of 8-Methoxypsoralen (8-MOP) b
Oxidation of 8-Methoxypsoralen (8-MOP) by Dimethyldioxirane. Evidence for the Formation of a Furocoumarin Epoxide by Methanol Trapping, a Potential Mutagenic Agent
✍ Adam, Waldemar ;Sauter, Markus 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 233 KB

## Abstract The reaction of 8‐methoxypsoralen (1) with dimethyldioxirane in methanol at 25^°^C yields the methanol adduct 3, namely the 2,3‐dihydro‐2‐hydroxy‐3,9‐dimethoxy‐7__H__‐furo[3,2‐__g__][1]benzopyran‐7‐one, whose structure was unequivocally assigned by means of spectroscopic data. Methanol