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Evidence of intramolecular hydrogen bonding in a complex N,N-disubstituted formamide

โœ Scribed by Richard E. Echols; Robert H. Miller; Derald Chriss; Ellen Vessel

Book ID
108007117
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
195 KB
Volume
39
Category
Article
ISSN
1386-1425

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The response of a hydrogen-bonded formamide-ammonia complex to an approaching water molecule has been studied by means of ab initio SCF molecular-orbital calculations. Depending on the site of interaction, the major hydrogen bond in the formamide-ammonia system undergoes modifications ranging from s