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Evidence for the Transition between Concerted and Stepwise Heterogeneous Electron Transfer−Bond Fragmentation Mechanisms

✍ Scribed by Antonello, Sabrina; Maran, Flavio


Book ID
127039538
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
182 KB
Volume
119
Category
Article
ISSN
0002-7863

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## Abstract The reduction of the bicyclic G‐factor endoperoxides G3 and G3Me was studied in __N__,__N__‐dimethylformamide using cyclic voltammetry and convolution analysis. Electron transfer leads to irreversible cleavage of the OO bond. Detailed analysis of the voltammetry curves reveals a non‐li