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Evidence for the Dominant Role of Secondary Orbital Interactions in Determining the Stereochemistry of the Diels-Alder Reaction: The Case of Cyclopropene

✍ Scribed by Apeloig, Yitzhak; Matzner, Eynatte

Book ID
121216518
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
786 KB
Volume
117
Category
Article
ISSN
0002-7863

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The Alder rule of maximum accumulation of unsaturation' has stimulated a number of rationalizations including stabilization of the & transition state of Diels-Alder reactions by (A) inductive (van der Waals or dipolar) forces2, (B) charge transfer,= (C) favorable geometry for