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Evidence for the 1,4-Addition of Hydrogen Halides to α,β-Unsaturated Ketones. The Dibenzoylmonohalogenoethylenes

✍ Scribed by Lutz, Robert E.; Wilder, Frank N.


Book ID
127212892
Publisher
American Chemical Society
Year
1934
Tongue
English
Weight
345 KB
Volume
56
Category
Article
ISSN
0002-7863

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1,4-Addition of triorganozincates and si
✍ Tückmantel, Werner ;Oshima, Koichiro ;Nozaki, Hitosi 📂 Article 📅 1986 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 683 KB

Lithium and magnesium triorganozincates, prepared by combination of ZnC12(TMEDA) with 3 molar equivalents of RLi or RMgX, or from dialkylzinc and 1 molar equivalent of RLi or RMgX, react with 2-cyclohexen-1-one (1) under mild conditions to produce moderate to good yields of the 1 &addition products