Evidence for syn addition of hydrogen chloride to phenylacetylene
β Scribed by F. Marcuzzi; G. Melloni; G. Modena
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 99 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Recently we described (1) the acid-catalyzed rearrangement of allene 1 to form a mixture of ring-opened isomers 2 (major) and 2 (minor); these conversions were rationalized as proceeding by the carbonium ion pathways shown. In particular, acid-catalyzed rearrangement of 2-methyl-3-(tetrsmethylcyclop
## Abstract Dyeβsensitized photooxygenations of 3 pairs of (__E__)/(__Z__) trisubstituted olefins were studied in order to establish the partitioning between the 3 possible ene additions. The (__E__)βisomers underwent only the 2 ene additions (>95%) involving Hβatom abstractions at the same, disubs