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Evidence for resonance collisions in rotational energy transfer; Raman lines of H2

โœ Scribed by R.A.J. Keijser; J.R. Lombardi; K.D. Van Den Hout; M. De Groot; B.C. Sanctuary; H.F.P. Knaap


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
178 KB
Volume
45
Category
Article
ISSN
0375-9601

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## Theoretuzal and elpenmentl analyas clearly shows that, m the gas phase, the lsotrop~c Raman Q lines of hydrogen molecules perturbed by argon exhhlblt, at IOU temperature, a vlbratlonal broadenmg resulting from the dephasing mechanism. Tius leads to a determmatlon of the correspondmg relaxaatlon

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Diffcrential cross sections of thc process Na\*(3 \*P) + M(u = 0) Na(3S) + M(u') have been mcasured for several molecules: Hz, D2, Nz, 02, CO, COz, NzO, Cz H4. WC observe two different types of enerpy spectra. One of them displays il typicalIy non-resonant elcctronic to vibrational energy transfer a