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Evidence for production of surface formate upon direct reaction of CO with alumina and magnesia

✍ Scribed by Pradip G. Gopal; Roger L. Schneider; Kenneth L. Watters


Book ID
113178275
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
511 KB
Volume
105
Category
Article
ISSN
0021-9517

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When starting with racemates, OY,,,,, = -l)i([j" + I ) , while for a sample ofcomposition (tl, I ) OY,,, = j([jd + 1) -2(/k/41'2)!tl(/1 -1). The optical yield can be related to the thermodynamic chirdl recognition. AAG = -RT1nl.i. as /j = [(I + OY)/(l -OY]' when d = l = I = 0.5 (0 s OY < 1 ). [12]