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Evidence for ion-neutral complex-mediated reactions well above the threshold for dissociation of the complex

✍ Scribed by David J. McAdoo; Charles E. Hudson

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 198 KB
Volume: 25
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210251207

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✦ Synopsis

The possibility that ion-neutral complex-mediated eliminations occur well above the threshold for simple dissociation of the partners in the complex was explored. This was accomplished by determining whether daughter ions of probable complex-mediated dissociations undergo metastable decompositions. All six complex-mediated decompositions examined formed metastable ions. Therefore, a very small fraction of ion-neutral complex-mediated fragmentations may occur several hundred kJ mol-above the threshold for dissociation of the partners.

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