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Evidence for hydrogen abstraction as the rate determining step in the photochemical reaction of SO2 with alkanes

โœ Scribed by Peter P. Smith; Leonard D. Spicer


Book ID
119020344
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
151 KB
Volume
6
Category
Article
ISSN
0045-6535

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Rate constants for hydrogen abstraction
โœ Robert E. Huie; Carol L. Clifton ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 451 KB ๐Ÿ‘ 1 views

Rate constants have been determined for the reactions of SO4with a series of alkanes and ethers. The SO, radical was produced by the laser-flash photolysis of persulfate, SZO: -. For methane, only an upper limit of 1 x lo6 M-' s-\* could be determined. For ethane, propane, and 2-methylpropane, rate

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Rate constants of Br atom reactions have been determined using a relative kinetic method in a 20 1 reaction chamber at total pressures between 25 and 760 torr in Nz + Oz diluent over the temperature range 293-355 K. The measured rate constants for the reactions with alkynes and alkenes showed depend