Rate constants have been determined for the reactions of SO4with a series of alkanes and ethers. The SO, radical was produced by the laser-flash photolysis of persulfate, SZO: -. For methane, only an upper limit of 1 x lo6 M-' s-\* could be determined. For ethane, propane, and 2-methylpropane, rate
โฆ LIBER โฆ
Evidence for hydrogen abstraction as the rate determining step in the photochemical reaction of SO2 with alkanes
โ Scribed by Peter P. Smith; Leonard D. Spicer
- Book ID
- 119020344
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 151 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0045-6535
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Rate constants of Br atom reactions have been determined using a relative kinetic method in a 20 1 reaction chamber at total pressures between 25 and 760 torr in Nz + Oz diluent over the temperature range 293-355 K. The measured rate constants for the reactions with alkynes and alkenes showed depend