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Evidence for facile and selective desulfurization: the reactions of 2,5-dihydrothiophene on molybdenum(110)

โœ Scribed by Liu, A. C.; Friend, Cynthia M.


Book ID
126211958
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
964 KB
Volume
113
Category
Article
ISSN
0002-7863

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## Acid hydrolysis of the ester function in A-( -)589-fi2-(RR)-[Co (trien) (glyOEt)C1I2+ (( -)-1) produces optically pure A-( -)589$2-(RR)-[CO (trien) (glyOH)C1I2+ (( -)-4). Hg2+ induced removal of chloride in (-)-4 follows the rate law kobs=kHg [Hg2+] with kHg=(1.36+0.03)x 1 0 -2 ~-l s -' , 25",