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Evidence for chain transfer in the atom transfer radical polymerization of butyl acrylate

✍ Scribed by Sebastian G. Roos; Axel H. E. Müller

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
56 KB
Volume
21
Category
Article
ISSN
1022-1336

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Polymerization of acrylates by atom transfer radical polymerization. Homopolymerization of 2-hydroxyethyl acrylate
✍ Simion Coca; Christina B. Jasieczek; Kathryn L. Beers; Krzysztof Matyjaszewski 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 188 KB

The application of atom transfer radical polymerization (ATRP) to the homopolymerization of 2-hydroxyethyl acrylate, a functional monomer, is reported. The polymerizations exhibit first-order kinetics, and molecular weights increase linearly with conversion. Polydispersities remain low throughout th