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Evidence for Au(I)…Au(I) Interactions in a Sterically Congested Environment: Two-Coordinate Gold(I) Halide Phosphine Complexes

✍ Scribed by Bott, Raymond C.; Healy, Peter C.; Smith, Graham


Book ID
121481579
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
2004
Tongue
English
Weight
992 KB
Volume
57
Category
Article
ISSN
0004-9425

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## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5‐disubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their