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Evidence for an imine-carbodiimide 1,2-cycloaddition adduct

โœ Scribed by Marvin W. Barker; Raymond H. Jones


Book ID
112122605
Publisher
Journal of Heterocyclic Chemistry
Year
1972
Tongue
English
Weight
85 KB
Volume
9
Category
Article
ISSN
0022-152X

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## Abstract The mechanisms of the title reactions between 1โ€azaโ€2โ€azoniaallene cations and carbodiimides in the gas phase have been examined using the Beckeโ€3โ€parameterโ€Leeโ€Yangโ€Parr (B3LYP) at 6โ€31++G\*\* level. The theoretical results revealed that the reaction is a domino reaction that comprises