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Evidence for an anomalous quantum state of protons in nanoconfined water

✍ Scribed by Reiter, G. F.; Kolesnikov, A. I.; Paddison, S. J.; Platzman, P. M.; Moravsky, A. P.; Adams, M. A.; Mayers, J.

Book ID
125852560
Publisher
The American Physical Society
Year
2012
Tongue
English
Weight
241 KB
Volume
85
Category
Article
ISSN
1098-0121

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Anomalously short fluorescence lifetimes
Anomalously short fluorescence lifetimes in jet cooled 4-hydroxyindole. Evidence for excited state tautomerism and proton transfer in clusters
✍ Yuhui Huang; Mark Sulkes πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 395 KB

Jet cooled fluorescence lifetimes following excitation of S I origins have been measured for 4-hydroxyindole. The subnanosecond values obtained are anomalous compared to other substituted indoles, in particular 5-hydroxyindole. The short lifetimes are most likely related to excited state tautomerism