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Evidence for a Tetraoxo Intermediate in a Reaction Between a Superoxometal Complex and Acylperoxyl Radicals

✍ Scribed by Pestovsky, Oleg; Harrata, Kamel A.; Bakac, Andreja

Book ID
126188794
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
54 KB
Volume
112
Category
Article
ISSN
1089-5639

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An excellent substrate of methylmalonyl-CoA mutase, methylmalonyl-carba-(dethia) coenzyme A (methylmalonyl-CH(2)-CoA), was synthesized by a chemoenzymatic method and its alpha-proton was exchanged with deuterium by long-term incubation in deuterium oxide at pH 6.9. After addition of highly purified