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Evidence for a protophosphatase catalysed cleavage of adenosine triphosphate by a dissociative-type mechanism within a receptor-substrate complex

✍ Scribed by G.Michael Blackburn; Gregory R.J Thatcher; Mir Wais Hosseini; Jean-Marie Lehn


Book ID
104227658
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
307 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


WY:

Analogues of ATP and diadencsine 5',5"' -Pl,P4+etraphosphate, Ap4A, have been used to explore the specificity and mechanism of the proto-ATPase activity of the macrocyclic polyamine [241-N602 (1).

The results shcw that (1) has exonuclease-like activity and support a mechanism that is dissociative in character within a pre-associative scheme resulting fran receptor-substrate binding.