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Evidence for a perepoxide intermediate in the 1,2-cycloaddition of singlet oxygen to adamantylideneadamantane: nucleophilic oxygen atom transfer to sulfoxides

✍ Scribed by Schaap, A. Paul; Recher, Scott G.; Faler, Gary R.; Villasenor, Steven R.


Book ID
126963998
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
378 KB
Volume
105
Category
Article
ISSN
0002-7863

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Evidence for a zwitterionic intermediate
✍ Roll Huisgen; Joaquin Plumet Ortega πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 193 KB

Tetracyanoethylene (TCNE) belongs to the most active dienophiles in . the Diels-Alder reaction.' Trans-fixed 1,3-dienes, however, combine with TCNE in 2+2 cycloadditions to give vinylcyclobutanes; 293 the second double bond effects an activation, No. 41 ACKNOWLEDGMENT. J.P.O. expresses his gratitude