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Evidence for a Diels-Alder reaction between dienes and olefins in the dehydrocyclodimerization of butene-1 on tellurium-loaded zeolites

✍ Scribed by Klaus D. Hungenberg; Josef H. Kagon; Bernd E. Langner


Book ID
113176510
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
197 KB
Volume
68
Category
Article
ISSN
0021-9517

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✍ G. Huybrechts; B. Van Mele 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB

Despite an extensive literature, controversy about the Diels-Alder reaction mechanism still exists. For the thermal dimerization of 1,3-butadiene, for example, a concerted one-step [I] or two-stage [2] mechanism, a mixture of orbital symmetry allowed and forbidden cycloadditions 131, as well as a tw