𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Evidence for a Cooper minimum in the photoionization dynamics of the NO D 2Σ+ state

✍ Scribed by Hongkun Park; Richard N. Zare

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
768 KB
Volume
225
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Rotationally resolved photoehtron angular distributions are reported for the two-color, two-photon process NO X 'lI (u,=O, Jg=17.5)+hv,+N0 D%+ (u-0, N=18)+hv,+NO+ X1X+ (v+ = 0, N + ) +e-. The positive and negative MT transitions (AN= N + -N) for the same value of 1 ANI markedly differ iu intensity and angular distribution. This observation indicates a strong energy dependence of the dynamical parameters that govern the photoionization of the NO D state and is consistent with the existence of a Cooper minimum in the 3po+m (I= 2) channel of the ionization continuum.

  1. IntrlnluctiolI

📜 SIMILAR VOLUMES

Dipole moments and electric field gradie
Dipole moments and electric field gradients for correlated wavefunctions of NO: The X 2Π, A 2Σ+, and D 2Σ+ states
✍ Stephen P. Walch; William A. Goddard III 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 738 KB

## Recent experiments by Bergeman and tire led to a dipole moment of l&l = 1 .lO k 0.03 D for the v = 3 vibrational level of the A\* C' stzte of NO, whereas conflgxation interaction (CI) stud& by Green led to p = 0.39 D (N+O-), a serious discrepancy. We report herein ab initjo generalized valence