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Evidence for a Carbonyl-Containing Intermediate in the 308-nm Photolysis of trans -RhCl(CO)(PMe 3 ) 2

โœ Scribed by Krishnan, R.; Schultz, Richard H.


Book ID
127120759
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
58 KB
Volume
44
Category
Article
ISSN
0020-1669

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Evidence for a zwitterionic intermediate
โœ Roll Huisgen; Joaquin Plumet Ortega ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

Tetracyanoethylene (TCNE) belongs to the most active dienophiles in . the Diels-Alder reaction.' Trans-fixed 1,3-dienes, however, combine with TCNE in 2+2 cycloadditions to give vinylcyclobutanes; 293 the second double bond effects an activation, No. 41 ACKNOWLEDGMENT. J.P.O. expresses his gratitude