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Evidence for a 1,4-hydrogen shift in a deuterium-labeled vinyl carbene intermediate in the formation of 1,3-pentadiene from 3,5-dimethylpyrazole

✍ Scribed by Perez, Jorge D.; Yranzo, Gloria I.


Book ID
126141744
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
136 KB
Volume
47
Category
Article
ISSN
0022-3263

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1,2,4,5-Tetra-l-butylbenzene (394) (TTBB) is believed to be a highly strained boat-shaped molecule (4) (I) and so might be expected to undergo photoisomerisation to a Dewar benzene (II) more readily than does 1,2,4-trit-butylbenzene(5'6), which was the first compound reported to undergo such a conve