Evidence for a 1,2-Hydrogen-Atom Migration in a Photochemically Generated Diradical 1,2
β Scribed by Schuster, David I.; Krull, Ira S.
- Book ID
- 126034775
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 247 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
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An excellent substrate of methylmalonyl-CoA mutase, methylmalonyl-carba-(dethia) coenzyme A (methylmalonyl-CH(2)-CoA), was synthesized by a chemoenzymatic method and its alpha-proton was exchanged with deuterium by long-term incubation in deuterium oxide at pH 6.9. After addition of highly purified
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