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Evaluation of the isomerization rates in the overdamped case

✍ Scribed by A.A. Villaeys; A. Boeglin; S.H. Lin

Book ID: 103022904
Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 499 KB
Volume: 116
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80156-1

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✦ Synopsis

We present a non-a&abatx model to study the vlscon~y effect on Isomeruation rates of molecules rn hqurds. The rate conslast oi rhese processes is fiis~ expressed m terms of correlation functions and the correlation functions for the degrees of freedom affected by solvent viseostty are calculated by usrng the Langevm equatron The wscosity dependence IS explicitly calculated In the overdamped case and exhibtts an asymptouc firute value for large wscos~ty. Theoretical results have been applied IO fit the expenmental data of Fleming et al. Volume 116. number 2,3 CHEh!ICAL PHYSICS LETTERS

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