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Evaluation of the electric field gradient at the 79Br site due to BrO2 radicals in Zn(BrO3)2 ·6H2O, Cd(BrO3)2 ·2H2O and Sr(BrO3)2 ·H2O

✍ Scribed by S. Ramaprabhu; K.V.S. Rama Rao; M.S. Gopinathan

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
291 KB
Volume
131
Category
Article
ISSN
0022-2860

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Cavity ring-down study of BrO radicals:
Cavity ring-down study of BrO radicals: Kinetics of the Br + O3 reaction and rate of relaxation of vibrationally excited BrO by collisions with N2 and O2
✍ Yuki Ninomiya; Satoshi Hashimoto; Masahiro Kawasaki; Timothy J. Wallington 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB 👁 2 views

Cavity ring-down (CRD) techniques were used to study the kinetics of the reaction of Br atoms with ozone in 1-205 Torr of either N 2 or O 2 , diluent at 298 K. By monitoring the rate of formation of BrO radicals, a value of k(Br ϩ O 3 ) ϭ (1.2 Ϯ 0.1) ϫ 10 Ϫ12 cm 3 molecule Ϫ1 s Ϫ1 was established th