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Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis

โœ Scribed by Bailey, Brad C.; Schrock, Richard R.; Kundu, Sabuj; Goldman, Alan S.; Huang, Zheng; Brookhart, Maurice


Book ID
111649852
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
118 KB
Volume
28
Category
Article
ISSN
0276-7333

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A Comparison of the Activity of Homogene
โœ C. vanโ€…Schalkwyk; H.โ€…C.โ€…M. Vosloo; J.โ€…A.โ€…K. duโ€…Plessis ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 178 KB

The W(O-2,6-C 6 H 3 X 2 ) 2 Cl 4 /Bu 4 Sn catalytic systems (X Ph, F, Cl, Br) have a high activity for the metathesis of terminal alkenes and a high selectivity towards primary metathesis products. Tungsten(VI) alkoxide complexes are not nearly as active as the tungsten(VI) aryloxide complexes. Brห˜n