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Evaluation of mercury porosimeter experiments using a network pore structure model

โœ Scribed by G.P. Androutsopoulos; R. Mann


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
981 KB
Volume
34
Category
Article
ISSN
0009-2509

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โœฆ Synopsis


A square network model has been developed to mterpret mercury penetratin and retraction behavlour m the widely employed mercury porosunetry technique for mvesbgatmg pore structure and pore SIX dlstnbubon A network of arbitrary sl~c IS constructed by assembhng cyhndncal pore segments of equal length and pseudorandom number generation IS used to assyn pore dmmeters accordmg to any stipulated sux distnbutlon fuactlon Apption of the sunpk Washburn cquanon then predlcts movement of mercury mto the network under mcreasmg pressure (peaetrahon) and the correspondmg mthdrawai under reducmg pressure (retraction) The network model IS supenor to the classical parallel bundle model, smce It ~mpl~ccrtly produces hysteresis between penetration and rctract~on. prticts that mercury entrapment on retraction IS a result of mtercoanectcdness of pore segments and provides a better estunate of the mtnnslc &stnbution of segment sizes Compmson wrath poroslmeter expernnents on a commercml hydrodesulphurmahon catalyst show that the approach can be apphed to practical measurements and the model may provide an reproved basis for the study of dlfluslon. reachon and deactivation m catalyst pellets


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