โ Scribed by F. Cappellani; G. Restelli; G. Melandrone
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The rate coefficients for the removal of C1 atoms by reaction with three HCFCs, CF3CHC12 (HCFC-123), CF3CHFCl (HCFC-124), and CH3CFC12 (HCFC 141b), were measured as a function of temperature between 276 and 397 K. CH3CF2C1 (HCFC-142b) was studied only a t 298 K. The Arrhenius expressions obtained ar
The kinetics of four gas-phase reactions involving halogenated methyl radicals (R,==CF,, CF2C1, CFCI,, and eel,) with molecular chlorine have been studied using a tuhular reactor coupled to a photoionization mass spectrometer. The radicals were homogeneously generated by the pulsed photolysis of pre
The first absolute rate measurerr,ents for the collisional quenching of the electronically excited oxygen atom, O(2 ' D2 1, by the atmospherically important fluorocarbons, CF2C12 and CFC13, are reported. O(2 ' D2) was generated by the repetitive pulsed irradiation of 03 in the Hartley-band continuum