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Evaluating the Stability of a Cationic Plastoquinone Derivative (PDTP) in Visomitin Eye Drops

✍ Scribed by D. A. Tsarev, R. S. Zverev, E. M. Kazmina, V. N. Tashlitsky, V. P. Skulachev


Book ID
120664535
Publisher
Springer
Year
2013
Tongue
English
Weight
241 KB
Volume
47
Category
Article
ISSN
0091-150X

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The orbital energy second derivatives with respect to the CC asymmetric stretching mode of benzene, allyl cation and allyl anion show unambigiously that the ~r orbitals are unstable with respect to a distorted geometry with alternating CC bonds. It is the cr frame which enforces the D6h form of benz