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Europium (II/III) on poly(styrene sulfonate) coated electrodes of stable electrochemical performance

✍ Scribed by Rainer Lange; Karl Doblhofer; Winfried Storck


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
239 KB
Volume
33
Category
Article
ISSN
0013-4686

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✦ Synopsis


A straight-forward method of preparing stable poly(styrene sulfonate) coatings on electrodes is described . The membrane-type thin film has a high permeability and ration-exchange capacity, as characterized by electrochemical methods with the redox-system Eu' -j' . The interactions between this redox-system and the polymer matrix are predominantly electrostatic in nature . 'The coating causes the electrochemical standard rate constant of the redox system to be reduced by one to two orders of magnitude .