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Etude stéréochimique du tricarbonyl[5a–9a-η-(méthyl-4 tétrahydro-3a,4,5,9b 1H-benz[e]indazolecarboxylate-3a de méthyle)]chrome(III), [Cr(C14H16N2O2)(CO)3]

✍ Scribed by Mercier, R. ;Douglade, J. ;Vebrel, J.


Book ID
114501649
Publisher
International Union of Crystallography
Year
1983
Tongue
English
Weight
447 KB
Volume
39
Category
Article
ISSN
0108-2701

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.