## Abstract The mass spectra of the O‐isopropylidene derivatives of __threo__‐ and __erythro__‐furanose and those of the four C(4) methylated stereoisomers have been studied. Fragmentation modes based upon deuterium labelling, metastable peaks and high‐resolution measurements are proposed. Each ste
Etude par spectrométrie de masse de la fragmentation du désoxy-3-di-O-isopropylidène-1,2: 5,6-méthylidène-3-α-D-hexofurannose et de quelques analogues substitués en C(3′)
✍ Scribed by Alain Glangetas; Fazil O. Gülacar; Jean M. J. Tronchet; Armand Buchs
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- German
- Weight
- 393 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Electron Impact Mass Spectrometry of the 3‐Desoxy‐1,2: 5,6‐di‐O‐isopropylidene‐3‐methylidene‐δ‐D‐hexofuranose and Some C(3′)‐Substituted Analogues
The mass spectra of the 3‐desoxy‐1,2:5, 6‐di‐O‐isopropylidene‐3‐methylidene‐ α‐D‐ribo‐hexofuranose and of some C(3′)‐mono‐ and ‐disubstituted derivatives have been investigated. Deuterium labelled molecules allow fragmentation modes to be proposed.
📜 SIMILAR VOLUMES
## Abstract Treatment of 3‐deoxy‐1, 2:5, 6‐di‐O‐isopropylidène‐3C‐méthylene‐α‐D‐ribo‐hexofuranose with aromatic nitrile oxides led to __spiro__‐Δ~2~‐isoxazolines, whereas a Δ~1~‐pyrazoline was obtained by reacting the same C‐methylenic sugar with diazomethane. Properties of these compounds, a new c