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Etude de L'Equilibre Azido → Tetrazole Dans la Serie du Thiazolo [2,3-e] Tetrazole I. Effets de Solvant

✍ Scribed by J. Elguero; R. Faure; J. P. Galy; E. J. Vincent


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
377 KB
Volume
84
Category
Article
ISSN
0037-9646

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✦ Synopsis


Abstract

The influence of solvent on the azido‐tetrazole equilibrium in thiazole series has been investigated by means of proton NMR spectroscopy. We made a hypothesis about the structure of the cation of azidothiazoles and we proposed that there is a rough parallelism between azido‐tetrazole isomerism and prototropic tautomerism.