ETS study of the negative ion states of t-butyl and trimethylsilyl derivatives of ethylene and benzene
✍ Scribed by Alberto Modelli; Derek Jones; Giuseppe Distefano
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 382 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Rcccwcd 4 November 1981, III Iin. fornl9 Dwcmbcr I981 Temporary negative-Ion foormatlon m 3,3'-chmcthyl-1-butenc, tr~methylsdylcthylcnc. r-butylbcnzcne and trnne(hylsdylbcnzcnc has been studled usmg electron transmission spectroscopy in the O-5 CV energy range. l-be previuhng effect on the II molecular ortntdls IS stabdaatlon ansmg from mterxuon wth low-lying unoccupied orbitals of the trrmethylsdyl group
📜 SIMILAR VOLUMES
## Abstract The 70 eV negative ion spectra of m‐ and p‐nitrophenyltrimethylsilyl‐ethers and ‐esters show pronounced molecular anions and simple fragmentation patterns. The spectra of the corresponding ortho isomers show peaks produced by rearrangement processes; these reactions have been studied by