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Ethylenimine Ketones. XI. 1 Steric Controls in the Formation of Isomeric Ethylenimine Ketones

✍ Scribed by Cromwell, Norman H.; Cahoy, Roger P.; Franklin, William E.; Mercer, Gerald D.


Book ID
121357479
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
690 KB
Volume
79
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Steric control in the base catalysed H-D
✍ Bruce A.W. Coller; W. Roy Jackson; Anna Stragalinou; JΕ±rgen U.G. Strauss πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 128 KB

For the base catalysed H-D exchange of the equatorial hydrogen and the axial hydrogen in 4-t-butyl-1-acetylcyclohex-l-ene (1) in CH30D containing CH30Na, keq/kax is 3.8:1. This is clearly a result of steric rather than stereoelectronic factors.