Polymerizations of styrene were carried out with half-sandwich complexes supported on silica, CpTiX 3 /MAO/SiO 2 (X Ο Cl, F). The optimum values for the polymerization time, the amount of cocatalyst and the Al support /Ti ratio were found for the trichlorinated system. The highest activity obtained
β¦ LIBER β¦
Ethylene Polymerization with Half-Sandwich Allyl Imido Complexes of Tantalum
β Scribed by Antonelli, David M.; Leins, Ann; Stryker, Jeffrey M.
- Book ID
- 127104421
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 136 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0276-7333
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## Abstract The synthesis of halfβsandwich transitionβmetal complexes containing the Cab^N^ and Cab^N,S^ chelate ligands (HCab^N^=HC~2~B~10~H~10~CH~2~C~5~H~4~N (1), LiCab^N,S^=LiSC~2~B~10~H~10~CH~2~C~5~H~4~N (4)) is described. Compounds 1 and 4 were treated with chlorideβbridged dimers [{Ir(Cp\*)Cl