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Ethylene polymerization with a catalytic system containing an organomagnesium compound

✍ Scribed by Ph. Radenkov; T. Petrova; L. Petkov; D. Jelyazkova


Book ID
111708545
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
125 KB
Volume
11
Category
Article
ISSN
0014-3057

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The PM3(tm) semiempirical method has been used to optimize the structures for the reactants and transition states of the first and second ethylene insertion processes into zirconocene catalytic systems. The results obtained for these reactions are compared with calculations published in the literatu