Ethylene Polymerization in the Presence of Iron(II) 2,6-Bis(imine)pyridine Complex: Structures of Key Intermediates
β Scribed by E. P. Talzi; D. E. Babushkin; N. V. Semikolenova; V. N. Zudin; V. A. Zakharov
- Book ID
- 110291517
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 82 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0023-1584
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## Abstract **Summary:** The polymerizations of ethyl vinyl ether, __n__βbutyl vinyl ether and isobutyl vinyl ether were investigated with a series of pyridine bis(imine) complexes of iron(II) and cobalt(II) in the presence of methylaluminoxane. The cobalt catalysts showed much higher activity and
The synthesis of the bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex was achieved from aqueous solution, and its characterization was performed by meanmf IR and CHN elemental analysis. Thermal polymerization of this complex was carried out in toluene and in solid state. The structu