Ethyl N -(2-acetyl-3-oxo-1-phenylbutyl)carbamate
✍ Scribed by Volov, Alexander N.; Zamilatskov, Ilia A.
- Book ID
- 121696386
- Publisher
- International Union of Crystallography
- Year
- 2013
- Tongue
- English
- Weight
- 532 KB
- Volume
- 69
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.047 wR factor = 0.145 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of the title compound, C 17 H 15 BrN 2 O 2 , has been determined at room temperature. The indole moiety is essentially planar and the structure is stabilized by intra-and intermolecular NÐHÁ Á ÁO hydrogen bonds.
## Abstract Intramolecular cyclization reactions were performed with 1‐(3‐oxo‐2‐phenylbutyl)‐1,2,5,6‐tetrahydropyridine derivatives 6a‐h in sulfuric acid to give 3,6‐diphenyl‐substituted 1‐aza‐bicyclo[3.3.1]nonadienes 9. The intermediate carbinols 7a‐f and 8b, c could be isolated. Carrying out the
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.062 wR factor = 0.168 Data-to-parameter ratio = 12.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.