In the title compound, C 19 H 21 N 3 O 3 , the pyrrolidine ring possesses an envelope conformation. The crystal packing is stabilized by N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds.
Ethyl 4-benzyloxycarbonyl-5-[2,2-bis(benzyloxycarbonyl)vinyl]-3-methylpyrrole-2-carboxylate
✍ Scribed by Senge, Mathias O. ;Smith, Kevin M.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 285 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C~25~H~24~N~2~O~3~S~3~, was crystallized from a methanol–acetone mixture. The monoclinic structure features one molecule in the asymmetric unit. The crystal packing is stabilized by π stacking.
The non-H atoms of the title molecule, C~13~H~14~N~2~O~3~, are approximately coplanar. The molecules are linked into a two-dimensional network parallel to the __bc__ plane by intermolecular N—H...O, C—H...O and C—H...π interactions.
The title compound, C 18 H 18 N 2 O 5 , was synthesized from 2,3dimethoxyphenylmethylidenemalononitrile and ethyl acetoacetate in the presence of triethylbenzylammonium chloride in an aqueous medium. The pyridone and benzene rings make a dihedral angle of 63.8 (1) . There are intermolecular C-HÁ Á Á
The title compound, C 39 H 38 N 2 O 4 , possesses crystallographically imposed C 2 symmetry, with the twofold axis bisecting the central benzene ring. There is an intramolecular hydrogen bond between the phenoxy O atom and the amide N atom.