𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Ethyl 4-(2-bromomethyl-5,5-dimethyl-1,3-dioxan-2-yl)-5-methylisoxazole-3-carboxylate

✍ Scribed by Twamley, Brendan ;Szabon-Watola, Monika ;Sharma, Shikha ;Natale, Nicholas R.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
386 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the structure of the title compound, C 14 H 20 BrNO 5 , at 90 (2) K, the isoxazole is an axial substituent of the chair conformation dimethyldioxanyl ring. There is an antiparallel arrangement of the isoxazole rings with an oxygen to ring centroid distance of 3.402 (6) A ˚.

📜 SIMILAR VOLUMES

ChemInform Abstract: Ethyl 5-Methyl-4-(2
ChemInform Abstract: Ethyl 5-Methyl-4-(2,5,5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate.
✍ Peiwen Zhou; James D. Fisher; Richard J. Staples; Ashwani Vij; Nicholas R. Natal 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

2,2-Dimethyl-5-(pyrrolidin-2-yl­idene)-1
2,2-Dimethyl-5-(pyrrolidin-2-yl­idene)-1,3-dioxane-4,6-dione
✍ Sabino, Jose R. ;Damasceno, Fabiano ;Cunha, Silvio 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 202 KB

This work describes the first solid-state structural study of a cyclic enaminone derivative from Meldrum's acid, C 10 H 13 NO 4 . The packing shows an infinite linear chain along [111] mediated by dimeric N-HÁ Á ÁO and nonclassical C-HÁ Á ÁO hydrogen-bonding interactions.