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Ether synthesis from alcohol and aldehyde in the presence of hydrogen and palladium deposited on charcoal

โœ Scribed by V. Bethmont; C. Montassier; P. Marecot


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
153 KB
Volume
152
Category
Article
ISSN
1381-1169

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A new method for the synthesis of ฮฑ-thio
โœ Tsuyoshi Satoh; Ko-ichi Kubota ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 148 KB

A two-step and high-yield method for the synthesis of ฮฑ-thio aldehydes from aldehydes with one-carbon elongation is realized by using chloromethyl phenyl sulfoxide as a one-carbon homologating agent. The ฮฑ-thio aldehydes are easily converted to desulfurized alcohols with Bu 3 SnH and AIBN in refluxi