The first synthesis of a water-soluble cationic sugar-substituted arene rhodium complex has been described. The w Ε½ . x water-soluble cationic rhodium complex was synthesized by the reaction of an ethanol solution of Rh COD Cl with 2 AgBF and then with phenyl-b-D-glucopyranoside. This water-soluble
(.eta.3-Oxaallyl)rhodium(I) Complexes as Catalyst Precursors for the Disproportionation of Aldehydes
β Scribed by Slough, Greg A.; Ashbaugh, John R.; Zannoni, Luke A.
- Book ID
- 127092680
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 877 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The rhodium thiopyrimidine complex [Rh(SPymMe 2 )(CO) 2 ] was tethered to chemically modified SiO 2 substrates and tested as a catalyst in the hydroformylation reaction of 1-heptene. Catalytic performance was monitored under different reaction conditions for several cycles, and compared with the cat
## Silica -supported catalytically active functional materials, such as the rhodium(I) carbene complex with 1-(triethoxysilylpropyl)-3-(2,4,6-trimethylbenzyl)imidazolidine-2-ylidine (L), were prepared using the sol-gel method. The complex (1; COD = 1,5-cyclooctadiene) RhCl(COD)[1-(triethoxysilylpr