Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4-Bis(4′-nitrofurazan-3′-yl)-2-oxofurazan (BNFOF) Using Non-isothermal Differential Scanning Calorimetry
✍ Scribed by Feng-Qi Zhao; Peng-Jiang Guo; Rong-Zu Hu; Hai Zhang; Zhi-Ming Xia; Hong-Xu Gao; Pei Chen; Yang Luo; Zhi-Zhong Zhang; Yan-Shui Zhou; Qin Xiao; Hong-An Zhao; Sheng-Li Gao; Qi-Zhen Shi; Gui-E Lu; Jin-Yong Jiang
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 189 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0256-7660
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✦ Synopsis
Abstract
A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4‐bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) with non‐isothermal differential scanning calorimetry (DSC) was presented. The rate equation for the decomposition of BNFOF was established, and information was obtained on the rate of temperature increase in BNFOF when the empiric‐order autocatalytic decomposition was converted into thermal explosion.