Rate constants for the reactions of C1 atoms and OH radicals with haloalkanes were measured using the relative rate technique. From these values the atmospheric lifetimes of the organics with respect to C1 atoms and OH radicals were calculated. C1 atoms were produced by the photolysis of chlorine ga
Estimation of OH radical reaction rate constants and atmospheric lifetimes for polychlorobiphenyls, dibenzo-p-dioxins, and dibenzofurans
β Scribed by Atkinson, Roger.
- Book ID
- 125480684
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 426 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0013-936X
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## Abstract Using a relative rate method, rate constants for the gasβphase reactions of the OH radical with __trans__βpinane [(1R, 2R)β2, 6, 6βtrimethylbicyclo[3.1.1]heptane], tricyclene (1, 7, 7βtrimethyltricyclo[2.2.1.0^2, 6^]heptane), and quadricyclane (quadricyclo[2.2.1.0^2, 6^.0^3, 5^]heptane)
## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__βC~3~H~7~ONO, __n__βC~4~H~9~ONO, and __n__βC~5~H~11~ONO have been determined at 298 Β± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat