Estimation of Kinetic Parameters for Hydrogenation Reactions Using a Genetic Algorithm

✍ Scribed by A. Kadiva; M. Taghi Sadeghi; R. Sotudeh-Gharebagh; M. Mahmudi

• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 150 KB
• Volume: 32
• Category: Article
• ISSN: 0930-7516
• DOI: 10.1002/ceat.200900070

✦ Synopsis

Abstract

The kinetics of acetylene hydrogenation in a fixed‐bed reactor of a commercial Pd/Al~2~O~3~ catalyst has been studied. The hydrogenation reactor considered in this work is an essential part of a vinyl chloride monomer (VCM) plant. Three well‐known kinetic models were used to simulate the hydrogenation reactor under industrial operating conditions. Since none of the models provide appropriate prediction, the industrial data and calculated values were compared and optimum kinetic parameters were evaluated utilizing a genetic algorithm (GA) technique. The best kinetic parameters for the three models were determined under specified industrial operating conditions. The hydrogenation reactor was simulated using the estimated optimum kinetic parameters of the three models. Simulation results from the three models were compared to industrial data and the best kinetic model was found. This kinetic model with the evaluated optimum kinetic parameters can well predict the behavior of the industrial hydrogenation reactor to improve the performance of the process.