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Estimation of cation binding properties in crown and lariat ether complexes using fast atom bombardment mass spectrometry

✍ Scribed by Toshio Takahashi; Akira Uchiyama; Kaoru Yamada; Bert C. Lynn; George W. Gokel


Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
280 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis


The complex&ion behavior of crown and lariat ethers with alkali metal ions has been assessed by means of FAB-mass spectrome@ and shown to cm-relate semi-quantitatively with findings obtained in the solution phase.


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## Using fast atom bombardment (FAB) mass spectrometry (MS), cross-chiral relationships were confirmed for the first time for the diasteromeric host-guest complexations between the chiral crown ether host (1) and the chiral organic ammonium ion guest (2) on the basis of the relative peak intensities