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Estimating Diffusion Coefficients of Probe Molecules into Polyelectrolyte Brushes by Electrochemical Impedance Spectroscopy

✍ Scribed by Rodríguez Presa, M. J.; Gassa, L. M.; Azzaroni, O.; Gervasi, C. A.

Book ID
126828559
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
671 KB
Volume
81
Category
Article
ISSN
0003-2700

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The electrochemical reduction of nitrate ions at a copper electrode in an unbuffered neutral aqueous solution is studied. Using a two compartment electrochemical cell, three stationary cathodic waves, noted P1, P2 and P3, were evidenced by cyclic voltammetry at -0.9, -1.2 and -1.3 V/SCE, respectivel